A new strategy for direct solution electrospinning of phosphorylated poly (vinyl chloride)/polyethyleneimine blend in alcohol media

Basit Öğe Kaydı
dc.authoridAltinkok, Cagatay/0000-0002-0262-4154
dc.authoridDurmaz, Hakan/0000-0003-4710-2496
dc.authoridDaglar, Ozgun/0000-0003-1526-1994
dc.authoridAcik, Gokhan/0000-0002-9427-0508
dc.authoridERCAN AYRA, Merve/0000-0001-5231-4659
dc.authorwosidAltinkok, Cagatay/ABA-9208-2020
dc.authorwosidDurmaz, Hakan/C-1124-2008
dc.authorwosidDaglar, Ozgun/H-2043-2018
dc.authorwosidAcik, Gokhan/M-5880-2019
dc.contributor.authorAltinkok, Cagatay
dc.contributor.authorSagdic, Gokhan
dc.contributor.authorDaglar, Ozgun
dc.contributor.authorAyra, Merve Ercan
dc.contributor.authorDurmaz, Yasemin Yuksel
dc.contributor.authorDurmaz, Hakan
dc.contributor.authorAcik, Gokhan
dc.date.accessioned2024-06-12T10:54:53Z
dc.date.available2024-06-12T10:54:53Z
dc.date.issued2023
dc.departmentTrakya Üniversitesien_US
dc.description.abstractPhosphorylated poly(vinyl chloride) (PPVC)/polyethyleneimine (PEI)-based nanofibers were produced via electrospinning in their blended solutions for the first time. For this purpose, PVC was partially converted into PVC-N3 and the PVC-N3 is then reacted with bis(diethoxyphosphoryl) acetylene (BDPA) via metal-free azide--alkyne 1,3-dipolar cycloaddition reaction to achieve the alcohol-soluble PPVC. PPVC and PEI solutions at certain concentrations prepared in methanol were electrospun from a single syringe at 90/10 and 85/15 vol ratios without phase separation. The accuracy of the modifications conducted on PVC was proven by Fourier-transform infrared (FT-IR), proton and carbon nuclear magnetic resonance (1H NMR and 13C NMR) spectros-copies and gel permeation chromatography (GPC), respectively. The achieved nanofibers and their intermediates were characterized by scanning electron microscope (SEM), water contact angle (WCA) measurement, ther-mogravimetric (TGA) and differential scanning calorimetry (DSC) analyses.The blood interaction of PPVC-PEI was evaluated through hemolysis and platelet activation assay, since most of the biomedical applications of PVC derivatives have close contact with blood. The results showed that PPVC-PEI nanofibers provide a safer surface for platelet with lower hemolytic activity compared to PPVC nanofibers. Therefore, PPVC-PEI-based electrospun nanofibers obtained by such an effective strategy exhibited a promising perspective for scientists in various biomedical purposes.en_US
dc.identifier.doi10.1016/j.eurpolymj.2022.111750
dc.identifier.issn0014-3057
dc.identifier.issn1873-1945
dc.identifier.scopus2-s2.0-85143700854en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1016/j.eurpolymj.2022.111750
dc.identifier.urihttps://hdl.handle.net/20.500.14551/19204
dc.identifier.volume183en_US
dc.identifier.wosWOS:000906246900001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofEuropean Polymer Journalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBlood-Contactingen_US
dc.subjectElectrospinningen_US
dc.subjectMetal-Freeazide-Alkyne 13-Dipolar Cycloaddi-Tionen_US
dc.subjectPoly (Vinyl Chloride)en_US
dc.subjectPolyethyleneimineen_US
dc.subjectPoly(Vinyl Chloride)en_US
dc.subjectPolyethyleneimineen_US
dc.subjectNanofibersen_US
dc.subjectNanoparticlesen_US
dc.subjectPvcen_US
dc.subjectPoly(Ethyleneimine)en_US
dc.subjectImmobilizationen_US
dc.subjectFabricationen_US
dc.subjectParticlesen_US
dc.subjectMembranesen_US
dc.titleA new strategy for direct solution electrospinning of phosphorylated poly (vinyl chloride)/polyethyleneimine blend in alcohol mediaen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu