Boz M.Çalişkan H.Zaim Ö.2024-06-122024-06-1220091300-0527https://search.trdizin.gov.tr/yayin/detay/89151https://hdl.handle.net/20.500.14551/17349Several ring expansion products carrying vinylic bromo functionality were synthesized by opening of the geminal dibromobicyclo[n.1.0]alkanes ring. Dibromocarbene was formed from bromoform and potassium tert-butoxide in hexane. Its reaction with various cyclic alkenes was the resultant dibromobicyclo[ n.1.0]alkanes. Then, opening was performed using AgNO3 in various solvent systems, such as acetic acid/DMSO, acetic acid/DMF, CH3OH/acetone, and H2O/DMF. © TÜBİTAK.eninfo:eu-repo/semantics/closedAccessBicyclic Compound; Carbene; Ring Expansion; Ring Opening; Vinylic HalideArticle33173782-s2.0-61849152347Q389151