Boz, MesutCaliskan, HafizeZaim, Oemer2024-06-122024-06-1220091300-0527https://doi.org/10.3906/kim-0807-3https://hdl.handle.net/20.500.14551/19505Several ring expansion products carrying vinylic bromo functionality were synthesized by opening of the geminal dibromobicyclo[n.1.0]alkanes ring. Dibromocarbene was formed from bromoform and potassium tert-butoxide in hexane. Its reaction with various cyclic alkenes was the resultant dibromobicyclo[n.1.0]alkanes. Then, opening was performed using AgNO3 in various solvent systems, such as acetic acid/DMSO, acetic acid/DMF, CH3OH/acetone, and H2O/DMF.en10.3906/kim-0807-3info:eu-repo/semantics/openAccessCarbeneBicyclic CompoundRing OpeningRing ExpansionVinylic HalideCatalyzed-ReactionsChiralityArticle3317378Q3WOS:000262865000008