Zaim, Ö2024-06-122024-06-1219990040-4039https://doi.org/10.1016/S0040-4039(99)01693-7https://hdl.handle.net/20.500.14551/23544Treatment of allylic alcohols with thiophosgene and pyridine gives thiolo chloroformates directly at room temperature, presumably via very rapid [3,3] sigmatropic rearrangements of thiono chloroformates. Synthesis of allyl thiono chloroformate from allyl alcohol, sodium hydride and thiophosgene at low temperature and warming up to room temperature supports this finding. (C) 1999 Elsevier Science Ltd. All rights reserved.en10.1016/S0040-4039(99)01693-7info:eu-repo/semantics/closedAccessRearrangementsAlcoholsThiocarbonylThiocarbamateDithiocarbonatesAlcoholsAcidsArticle404680598062Q2WOS:0000833427000062-s2.0-0033550255Q3