Synthesis of Soybean Oil Biomass Main Chain Poly(Acrylic Acid)-Poly(?-Caprolactone) Based Heterograft Copolymer by Simultaneous Photo-Induced Metal-Free ATRP and Ring-Opening Polymerizations

Basit Öğe Kaydı
dc.authoridAcik, Gokhan/0000-0002-9427-0508
dc.authorwosidAcik, Gokhan/M-5880-2019
dc.contributor.authorAcik, Gokhan
dc.date.accessioned2024-06-12T11:12:21Z
dc.date.available2024-06-12T11:12:21Z
dc.date.issued2023
dc.departmentTrakya Üniversitesien_US
dc.description.abstractA photo-induced and completely metal catalyst-free synthetic pathway is proposed for the preparation of bio-based heterograft copolymer based on poly(acrylicacid) (PAA) and poly(epsilon-caprolactone) (PCL) pendant groups on the soybean oil (SBO) backbone (PAA-SBO-PCL). For this purpose, the SBO possessing primary hydroxyland bromide functionalities (Br-SBO-OH) is prepared from epoxidized soybean oil(ESBO) by ring-opening reaction catalyzed by hydrochloric acid. The photo-inducedmetal-free atom transfer radical and ring-opening photopolymerizations (PIMF-ATRP and PIMF-ROP) of tertiary butylacrylate (t-BA) and epsilon-CL monomers are concurrently performed on the Br-SBO-OH bifunctional macro photo-initiator without affecting each other, using perylene as an organic photo-catalyst (lambda= 400-500 nm). The t-BA groups of resulting bio-based PtBA-SBO-PCL is hydrolyzed into acrylic acid moieties via acidolysisto achieve the ultimate PAA-SBO-PCL. Spectroscopic, chromatographic,wettability and thermal investigations such as FT-IR, H-1-NMR, GPC,WCA, TGA and DSC analyses indicate that both the required intermediates and thetargeted polymers are successfully synthesized, as well as the conversion of t-BA groups to acrylic acid units. Thus,this efficient and most importantly green and sustainable process that can beenabled to production of a variety of SBO-based heterograft copolymers could greatly expand the potential applications of widely used polymers as advanced materials.en_US
dc.identifier.doi10.1007/s10924-022-02630-y
dc.identifier.endpage111en_US
dc.identifier.issn1566-2543
dc.identifier.issn1572-8919
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-85140327437en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage102en_US
dc.identifier.urihttps://doi.org/10.1007/s10924-022-02630-y
dc.identifier.urihttps://hdl.handle.net/20.500.14551/23145
dc.identifier.volume31en_US
dc.identifier.wosWOS:000871172300003en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal Of Polymers And The Environmenten_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhotopolymerizationen_US
dc.subjectAtom Transfer Radical Polymerizationen_US
dc.subjectRing-Opening Polymerizationen_US
dc.subjectSoybean Oilen_US
dc.subjectThermal Propertiesen_US
dc.subjectControlled/Living Radical Polymerizationen_US
dc.subjectBlock-Copolymersen_US
dc.subjectNanoparticlesen_US
dc.subjectWettabilityen_US
dc.subjectTemperatureen_US
dc.subjectPolymersen_US
dc.subjectMonomersen_US
dc.subjectRouteen_US
dc.titleSynthesis of Soybean Oil Biomass Main Chain Poly(Acrylic Acid)-Poly(?-Caprolactone) Based Heterograft Copolymer by Simultaneous Photo-Induced Metal-Free ATRP and Ring-Opening Polymerizationsen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu