A facile approach for the fabrication of antibacterial nanocomposites: A case study for AgNWs/Poly(1,4-Cyclohexanedimethylene Acetylene Dicarboxylate) composite networks by aza-Michael addition

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dc.authoridAcik, Gokhan/0000-0002-9427-0508
dc.authoridAltinkok, Cagatay/0000-0002-0262-4154
dc.authoridDurmaz, Hakan/0000-0003-4710-2496
dc.authoridDaglar, Ozgun/0000-0003-1526-1994
dc.authorwosidAcik, Gokhan/M-5880-2019
dc.authorwosidAltinkok, Cagatay/ABA-9208-2020
dc.authorwosidDurmaz, Hakan/C-1124-2008
dc.authorwosidDaglar, Ozgun/H-2043-2018
dc.contributor.authorAltinkok, Cagatay
dc.contributor.authorAcik, Gokhan
dc.contributor.authorDaglar, Ozgun
dc.contributor.authorDurmaz, Hakan
dc.contributor.authorTunc, Ilknur
dc.contributor.authorAgel, Esra
dc.date.accessioned2024-06-12T10:51:54Z
dc.date.available2024-06-12T10:51:54Z
dc.date.issued2022
dc.departmentTrakya Üniversitesien_US
dc.description.abstractNanotechnological improvements allow the production of new generation materials among which nanocomposite-based polymers are increasingly applied for wide variety of applications due to the demand increment of improving life quality of mankind. This article describes a simple, facile and fast route which could be adopted for the synthesis of metal nanocomposite materials with a variety of polymers. In this purpose, the cysteamine compound containing an amine (NH2) and a thiol (-SH) functional groups was incorporated onto silver nanowires (NH2-AgNWs). Next, poly(1,4-Cyclohexanedimethylene Acetylene Dicarboxylate) (PCA) possessing electron deficient internal alkyne moiety is synthesized starting from acetylene dicarboxylic acid (ADCA). Finally, one-pot aza-Michael addition is then realized between prepared NH2-AgNWs and synthesized PCA to achieve a series of cross-linked antibacterial nanocomposite networks (PCA:NH2-AgNWs = 1; 5; 10 wt%). The nanocomposites and intermediates are fully characterized by Fourier transform infrared and proton nuclear magnetic resonance (FT-IR, 1H NMR) spectroscopies, gel permeation chromatography (GPC) scanning electron microscopy (SEM), Energy-dispersive X-ray spectroscopy (EDS), thermogravimetric and differential scanning calorimetry analyses (TGA and DSC) and antibacterial test. The results reveal that the higher content of AgNWs in the network has occasioned the enhancement in thermostability and glass transition temperature. The antibacterial efficacy tests against Escherichia coli (E. coli, G) and Staphylococcus aureus (S.aureus, G +) further indicate that higher rate of inhibition is attained for nanocomposite network including 10 wt% AgNWs compared to others and pristine PCA. Consequently, a polyester based AgNWs/PCA nanocomposite with antibacterial activity has been considered as a versatile candidate for various promising nanocomposite applications.en_US
dc.identifier.doi10.1016/j.eurpolymj.2022.111130
dc.identifier.issn0014-3057
dc.identifier.issn1873-1945
dc.identifier.scopus2-s2.0-85126463727en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1016/j.eurpolymj.2022.111130
dc.identifier.urihttps://hdl.handle.net/20.500.14551/18521
dc.identifier.volume169en_US
dc.identifier.wosWOS:000911464400001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofEuropean Polymer Journalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAntibacterial Activityen_US
dc.subjectNanocomposite Silver Nanowiresen_US
dc.subjectThermal Propertiesen_US
dc.subjectSilver Nanoparticlesen_US
dc.subjectPolyesteren_US
dc.subjectPolymerizationen_US
dc.subjectPolypropyleneen_US
dc.subjectTransparenten_US
dc.subjectNanofibersen_US
dc.subjectPowerfulen_US
dc.subjectChitosanen_US
dc.subjectFilmen_US
dc.subjectToolen_US
dc.titleA facile approach for the fabrication of antibacterial nanocomposites: A case study for AgNWs/Poly(1,4-Cyclohexanedimethylene Acetylene Dicarboxylate) composite networks by aza-Michael additionen_US
dc.typeArticleen_US

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