Spectroscopic characterization of Cu(II) complex of L-phenylalanine and D,L-tryptophan

Küçük Resim Yok

Tarih

2010

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Pergamon-Elsevier Science Ltd

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

In this work, the reactions involving L-phenylalanine and D,L-tryptophan in the presence of Cu(II) ion were studied. Optimum conditions for the reactions were established as pH 7 and lambda=641 nm. When the reaction was kinetic, it was observed that the following rate formula was found as dA/A(n) = kdt and k = 3.2 x 10(-4) s(-1), according to absorbance measurements. Using a perpetual change curve, the ratio of [Cu]/[Cu] +L-phenylalanine + [D,L-tryptophan] was found 1:1:1. According to this result, one molecule of L-phenylalanine and one molecule of D,L-tryptophan react with one molecule Cu(II) ion. (C) 2009 Elsevier B.V. All rights reserved.

Açıklama

Anahtar Kelimeler

L-Phenylalanine, D,L-Tryptophan, Copper(II), Spectrophotometry, Reaction Kinetic, Carbon-Paste Electrode, Tryptophan, Acid, Cytotoxicity, Nicotinamide, Equilibrium, Hydrolysis, Cysteine, Crystal, Leucine

Kaynak

Spectrochimica Acta Part A-Molecular And Biomolecular Spectroscopy

WoS Q Değeri

Q2

Scopus Q Değeri

Q2

Cilt

75

Sayı

2

Künye