Vapor-induced film formation from low-Tg particles for different solvent compositions

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dc.authoridSarac, A.Sezai/0000-0001-7513-1740
dc.authoridPEKCAN, Onder/0000-0002-0082-8209
dc.authorwosidSarac, A.Sezai/N-1628-2014
dc.authorwosidPEKCAN, Onder/Y-3158-2018
dc.contributor.authorArda, Ertan
dc.contributor.authorKara, Selim
dc.contributor.authorSarac, Ayfer
dc.contributor.authorPekcan, Onder
dc.date.accessioned2024-06-12T11:02:01Z
dc.date.available2024-06-12T11:02:01Z
dc.date.issued2006
dc.departmentTrakya Üniversitesien_US
dc.description.abstractThe photon transmission method was used to study latex film formation from poly(vinyl acetate) (PVAc) particles induced by two different solvents. Films with the same latex content were prepared from PVAc particles and exposed to vapor of ethanol-water and acetone-water mixtures in various compositions. Transmitted photon intensities, I-tr, from these films increased with increasing vapor exposure time. The increase in I-tr is attributed to the increase in crossing density at the polymer-polymer junction. The Prager-Tirrell model was employed to obtain the back-and-forth frequency, v, of the reptating polymer chain during film formation induced by solvent vapor. It was observed that the produced v values increase as the solvent content is increased for both solvents. Abilities of both solvents to form films were interpreted with the solubility parameters of the solvents and the PVAc. (c) 2005 Elsevier Inc. All rights reserved.en_US
dc.identifier.doi10.1016/j.jcis.2005.10.042
dc.identifier.endpage524en_US
dc.identifier.issn0021-9797
dc.identifier.issn1095-7103
dc.identifier.issue2en_US
dc.identifier.pmid16310210en_US
dc.identifier.scopus2-s2.0-33646059882en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage520en_US
dc.identifier.urihttps://doi.org/10.1016/j.jcis.2005.10.042
dc.identifier.urihttps://hdl.handle.net/20.500.14551/21094
dc.identifier.volume297en_US
dc.identifier.wosWOS:000237529000016en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherAcademic Press Inc Elsevier Scienceen_US
dc.relation.ispartofJournal Of Colloid And Interface Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectFilm Formationen_US
dc.subjectSolvent Vaporen_US
dc.subjectChain Reptationen_US
dc.subjectReptation Frequencyen_US
dc.subjectPolymer Diffusionen_US
dc.subjectLatex Filmsen_US
dc.subjectInterdiffusionen_US
dc.subjectTransmissionen_US
dc.subjectInterfacesen_US
dc.subjectReptationen_US
dc.titleVapor-induced film formation from low-Tg particles for different solvent compositionsen_US
dc.typeArticleen_US

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