Polypropylene-based graft copolymers via CuAAC click chemistry

Basit Öğe Kaydı
dc.authoridAcik, Gokhan/0000-0002-9427-0508;
dc.authorwosidAcik, Gokhan/M-5880-2019
dc.authorwosidTasdelen, Mehmet Atilla/B-8338-2008
dc.contributor.authorAcik, G.
dc.contributor.authorSey, E.
dc.contributor.authorTasdelen, M. A.
dc.date.accessioned2024-06-12T11:12:34Z
dc.date.available2024-06-12T11:12:34Z
dc.date.issued2018
dc.departmentTrakya Üniversitesien_US
dc.description.abstractGraft copolymers from commercial chlorinated polypropylene (PP-Cl) possessing either poly(ethylene glycol) (PEG) or poly(epsilon-caprolactone) (PCL) grafts are synthesized by copper (I)-catalyzed azide-alkyne cycloaddition 'click' reaction (CuAAC). For this purpose, azido-functional polypropylene is prepared by nucleophilic substitution of chlorine groups of PP-Cl with azidotrimethylsilane-tetrabutylammonium fluoride. Whereas, the clickable alkyne end-functional PEG and PCL are independently synthesized by esterification reaction of poly(ethylene glycol) methyl ether with 4-pentyonic acid at room temperature and ring-opening polymerization of epsilon-caprolactone using stannous octoate as catalyst and propargyl alcohol as initiator. Finally, the corresponding graft copolymers, PP-g-PEG and PP-g-PCL, with different surface properties were successfully synthesized by CuAAC 'click' reaction under mild condition. Spectral, chromatographic and thermal analyses at various stages prove the formation of desired polypropylene-based graft copolymers with well-defined properties. Furthermore, the water contact angle values of PP-Cl, PP-g-PEG and PP-g-PCL are found as 90 +/- 1 degrees, 78 +/- 1.8 degrees and 83 +/- 2.1 degrees, respectively.en_US
dc.description.sponsorshipTurkish Scientific and Technical Research Council (TUBITAK) [216Z060]en_US
dc.description.sponsorshipOne of the authors (G. A.) would like to acknowledge and thank Turkish Scientific and Technical Research Council (TUBITAK, Project No: 216Z060) by means of 1002-Short Term R&D Funding Program for financial support. The authors would like to thank to Dr. Elif Ozen Cansoy from Piri Reis University for WCA measurements.en_US
dc.identifier.doi10.3144/expresspolymlett.2018.35
dc.identifier.endpage428en_US
dc.identifier.issn1788-618X
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-85044959385en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage418en_US
dc.identifier.urihttps://doi.org/10.3144/expresspolymlett.2018.35
dc.identifier.urihttps://hdl.handle.net/20.500.14551/23216
dc.identifier.volume12en_US
dc.identifier.wosWOS:000429069000003en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherBudapest Univ Technol & Econen_US
dc.relation.ispartofExpress Polymer Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectPolymer Synthesisen_US
dc.subjectChlorinated Polypropyleneen_US
dc.subjectCopper (I)-Catalyzed Azide-Alkyne Cycloadditionen_US
dc.subjectGraft Copolymersen_US
dc.subjectWater Contact Angleen_US
dc.subjectTransfer Radical Polymerizationen_US
dc.subjectSurface Modificationen_US
dc.subjectOlefin Polymerizationen_US
dc.subjectMechanical-Propertiesen_US
dc.subjectPolyolefinsen_US
dc.subjectPolyethyleneen_US
dc.subjectBlocken_US
dc.subjectPolymersen_US
dc.subjectFilmsen_US
dc.subjectNanocompositesen_US
dc.titlePolypropylene-based graft copolymers via CuAAC click chemistryen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu