Thermodynamics of dissociation of strontium, barium and nickel caproates in water
Küçük Resim Yok
Tarih
1997
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Scientific Technical Research Council Turkey
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The critical micellar concentration (CMC) and thermodynamic parameters (heat Delta H-d, free energy Delta G(d), and entropy Delta S-d, of dissociation) of aqueous solutions of strontium, barium and nickel caproates were determined by conductivity measurements. A Kraus and Bray-type expression was used to evaluate molecular conductance at infinite dilution and theromdynamic parameters. The results confirm that CMC remains unaffected by temperature in the range of 25-55 degrees C, and show that the dissociation of soaps is an exothermic reaction and nonspontaneous.
Açıklama
Anahtar Kelimeler
Critical Micellar Concentration, Conductance, Dissociation, Barium, Nickel And Strontium Caproate, Thermodynamics
Kaynak
Turkish Journal Of Chemistry
WoS Q Değeri
Q4
Scopus Q Değeri
N/A
Cilt
21
Sayı
3
