Diethoxy-azobis(pyridinium) salt as photoinitiator for cationic polymerization

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dc.authoridYagci, Yusuf/0000-0001-6244-6786
dc.authoridZaim, Omer/0000-0002-3472-5611
dc.authorwosidZaim, Ömer/AAI-1470-2021
dc.authorwosidYagci, Yusuf/AAT-6283-2021
dc.authorwosidYagci, Yusuf/C-1143-2008
dc.authorwosidZaim, Omer/Q-7770-2019
dc.contributor.authorDurmaz, Yasemin Yuksel
dc.contributor.authorZaim, Oemer
dc.contributor.authorYagci, Yusuf
dc.date.accessioned2024-06-12T10:51:13Z
dc.date.available2024-06-12T10:51:13Z
dc.date.issued2008
dc.departmentTrakya Üniversitesien_US
dc.description.abstractN,N'-diethoxy-4,4'-azobis(pyridinium) hexafluorophosphate (DEAP) has been synthesized by alkylation of the corresponding N-oxide and characterized. DEAP exhibits UV induced cis-trans isomerization with absorptions at around lambda = 459 and 360 nm, respectively. The ability of the DEAP ion to act as a photoinitiator for the cationic polymerization of cyclohexene oxide and N-vinylcarbazole is demonstrated. The initiation step involves the decay of the excited state of the trans form of the salt with homolytic bond rupture of the nitrogen-oxygen bond. Its potential use as a photoinitiator for free radical polymerization is also demonstrated using methyl methacrylate monomer as the example.en_US
dc.identifier.doi10.1002/marc.200800070
dc.identifier.endpage896en_US
dc.identifier.issn1022-1336
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-55349142480en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage892en_US
dc.identifier.urihttps://doi.org/10.1002/marc.200800070
dc.identifier.urihttps://hdl.handle.net/20.500.14551/18283
dc.identifier.volume29en_US
dc.identifier.wosWOS:000257377600005en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofMacromolecular Rapid Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAlkoxy Pyridinium Salten_US
dc.subjectCationic Photopolymerizationen_US
dc.subjectCis-Trans Isomersen_US
dc.subjectPhotopolymerizationen_US
dc.subjectN-Alkoxy-Pyridiniumen_US
dc.subjectBlock Copolymerizationen_US
dc.subjectCyclohexene Oxideen_US
dc.subjectInitiatorsen_US
dc.subjectDialkylphenacylsulfoniumen_US
dc.subjectPolymersen_US
dc.subjectSystemsen_US
dc.subjectLighten_US
dc.titleDiethoxy-azobis(pyridinium) salt as photoinitiator for cationic polymerizationen_US
dc.typeArticleen_US

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