Mathematical Characterization of Thermo-reversible Phase Transitions of Agarose Gels
Küçük Resim Yok
Tarih
2018
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor & Francis Inc
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The thermal phase transition temperatures of high (HMP) and low melting point (LMP) agarose gels were investigated by using UV-vis spectroscopy techniques. Transmitted light intensities from the gel samples with different agarose concentrations were monitored during the heating (gel-sol) and cooling (sol-gel) processes. It was observed that the transition temperatures, T-m, defined as the location of the maximum of the first derivative of the sigmoidal transition paths obtained from the UV-vis technique, slightly increased by increasing the agarose concentration in both the HMP and LMP samples. Here, we express the phase transitions of the agar-water system, as a representative of reversible physical gels, in terms of a modified Susceptible-Infected-Susceptible epidemic model whose solutions are the well-known 5-point sigmoidal curves. The gel point is hard to determine experimentally and various computational techniques are used for its characterization. Based on previous work, we locate the gel point, T-0, of sol-gel and gel-sol transitions in terms of the horizontal shift in the sigmoidal transition curve. For the gel-sol transition (heating), T-0 is greater than T-m, i.e. later in time, and the difference between T-0 and T-m is reduced as the agarose content increases. For the sol-gel transition (cooling), T-0 is again greater than T-m, but it is earlier in time for all agarose contents and moves forward in time and gets closer to T-m as the agarose content increases.
Açıklama
Anahtar Kelimeler
Agarose, Gel Point, Generalized Logistic Curve, Sol-Gel And Gel-Sol Transition, Kappa-Carrageenan Gels, Gelation Mechanism, Epidemic Models, Helix, Fluorescence, Networks, Systems
Kaynak
Journal Of Macromolecular Science Part B-Physics
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
57
Sayı
5
