Synthesis, properties and biodegradability of cross-linked amphiphilic Poly (vinyl acrylate)-Poly(tert-butyl acrylate)s by photo-initiated radical polymerization

Basit Öğe Kaydı
dc.authoridAcik, Gokhan/0000-0002-9427-0508
dc.authoridKARATAVUK, Ali Osman/0000-0001-6616-4065
dc.authorwosidAcik, Gokhan/M-5880-2019
dc.authorwosidKARATAVUK, Ali Osman/AAE-8175-2019
dc.contributor.authorAcik, Gokhan
dc.contributor.authorKaratavuk, Ali Osman
dc.date.accessioned2024-06-12T10:51:28Z
dc.date.available2024-06-12T10:51:28Z
dc.date.issued2020
dc.departmentTrakya Üniversitesien_US
dc.description.abstractThe novel amphiphilic poly(vinyl acrylate)-poly(tert-butyl acrylate) based networks are produced by light-induced photo-initiated radical polymerization between poly(vinyl acrylate) (PVAcr), obtained by using hydroxyl moieties of poly(vinyl alcohol) (PVA), and tert-Butyl acrylate (tBA) monomer. PVA is modified by acryloyl chloride to obtained the corresponding acrylate functionalities (PVAcr). The achieved PVAcr is crosslinked with different amount of tBA (PVAcr:tBA = 0.005:1 and 0.005:2 by mole) to give desired structures (PVAcr-PtBA-1 and PVAcr-PtBA-2) in the presence of 2,2-Dimethoxy-2-phenylacetophenone (DMPA) at lambda = 350 nm under nitrogen atmosphere. The structure, wettability, thermal and biodegradability properties of the pristine PVA and achieved networks are evaluated as a function of tBA loading by Fourier transform infrared (FT-IR) spectroscopy, water contact angle (WCA) measurement, thermogravimetric (TGA) and differential scanning calorimetry (DSC) analyses and biodegradation test, respectively. The results indicate that PVAcr-PtBA-2 obtained by higher tBA loading is less hydrophilic and biodegradable, but have improved thermal properties compared to pure PVA, and PVAcr-PVAcr control sample and PVAcr-PtBA-1.en_US
dc.identifier.doi10.1016/j.eurpolymj.2020.109602
dc.identifier.issn0014-3057
dc.identifier.issn1873-1945
dc.identifier.scopus2-s2.0-85081006067en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1016/j.eurpolymj.2020.109602
dc.identifier.urihttps://hdl.handle.net/20.500.14551/18378
dc.identifier.volume127en_US
dc.identifier.wosWOS:000525871600011en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofEuropean Polymer Journalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAmphiphilicen_US
dc.subjectBiodegradabilityen_US
dc.subjectPhoto-Initiated Radical Polymerizationen_US
dc.subjectPoly(Vinyl Alcohol)en_US
dc.subjectThermal Propertiesen_US
dc.subjectPolyvinyl-Alcoholen_US
dc.subjectPoly(Vinyl Alcohol)en_US
dc.subjectCopolymersen_US
dc.subjectFabricationen_US
dc.subjectMechanismen_US
dc.subjectGrapheneen_US
dc.titleSynthesis, properties and biodegradability of cross-linked amphiphilic Poly (vinyl acrylate)-Poly(tert-butyl acrylate)s by photo-initiated radical polymerizationen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu