Antibacterial film from chlorinated polypropylene via CuAAC click chemistry

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dc.contributor.authorAcik, Gokhan
dc.contributor.authorAltinkok, Cagatay
dc.contributor.authorOlmez, Hulya
dc.contributor.authorTasdelen, Mehmet Atilla
dc.date.accessioned2019-06-24T13:18:56Z
dc.date.available2019-06-24T13:18:56Z
dc.date.issued2018
dc.departmentFakülteler, Fen Fakültesi, Kimya Bölümüen_US
dc.descriptionAltinkok, Cagatay (Trakya Author)en_US
dc.description.abstractPolypropylene possessing quaternary ammonium salt (PP-QAS) is synthesized by copper (I)-catalyzed azide-alkyne cycloaddition "click" reaction (CuAAC) starting from chlorinated polypropylene (PP-Cl). The antibacterial properties of PP-QAS have been investigated on gram-positive (Staphylococcus aureus) and gram-negative (Escherichia colt) bacteria. For this purpose, clickable azide functionality has been introduced into PP-Cl backbone by using azidotrimethylsilane (TMS-N-3) - tetrabutylammonium fluoride solution (TBAF) system in tetrahydrofuran (THF) (PP-N-3). Independently clickable alkyne functionalized QAS is prepared by the reaction between 3-dimethylamino-1-propyne and benzyl bromide in the presence of triethyl amine (TEA). Finally, the polypropylene film containing quaternary ammonium salt (PP-QAS) is prepared by the successive CuAAC click reaction and solution casting method. The preparation of PP-QAS is monitored by fourier transform infrared (FT-IR) spectroscopy, proton nuclear magnetic resonance (H-1-NMR), differential scanning calorimetry (DSC) and scanning electron microscope (SEM) analyses at various stages. Based on antibacterial activity experiments, the PP-QAS coupons significantly inhibit both the growth of S. aureus and E. coli (p < 0.05) compared to neat PP-CI and control samples.en_US
dc.identifier.citationAcik, G., Altinkok, C., Olmez, H., & Tasdelen, M. A. (2018). Antibacterial film from chlorinated polypropylene via CuAAC click chemistry. Progress in Organic Coatings, 125, 73-78.en_US
dc.identifier.doi10.1016/j.porgcoat.2018.08.029en_US
dc.identifier.endpage78en_US
dc.identifier.scopus2-s2.0-85052871666en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage73en_US
dc.identifier.urihttps://doi.org/10.1016/j.porgcoat.2018.08.029
dc.identifier.urihttps://hdl.handle.net/20.500.14551/4192
dc.identifier.volume125en_US
dc.identifier.wosWOS:000453642900009en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofJournal Citation Reportsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.snmz20240608_ID_Qen_US
dc.subjectAntibacterial Activityen_US
dc.subjectChlorinated Polypropyleneen_US
dc.subjectCopper (I)-Catalyzed Azide-Alkyneen_US
dc.subjectCycloadditionen_US
dc.subjectPolypropyleneen_US
dc.subjectBiologically-Active Polycationsen_US
dc.subjectTransfer Radical Polymerizationen_US
dc.subjectIsotactic Polypropyleneen_US
dc.subjectGraften_US
dc.subjectFunctionalizationen_US
dc.subjectCopolymersen_US
dc.subjectSurfaceen_US
dc.subjectMonomersen_US
dc.subjectFacileen_US
dc.subjectFibersen_US
dc.titleAntibacterial film from chlorinated polypropylene via CuAAC click chemistryen_US
dc.typeArticleen_US

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