Preparation and characterization of phosphine oxide based polyurethane/silica nanocomposite via non-isocyanate route

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dc.authoridGungor, Atilla/0000-0001-9562-6265
dc.authorwosidGUNGOR, Ali/AAW-9172-2020
dc.authorwosidmenceloglu, yusuf Z/A-6545-2017
dc.contributor.authorHosgor, Zuhal
dc.contributor.authorKayaman-Apohan, Nilhan
dc.contributor.authorKaratas, Sevim
dc.contributor.authorMenceloglu, Yusuf
dc.contributor.authorGungor, Atilla
dc.date.accessioned2024-06-12T11:08:57Z
dc.date.available2024-06-12T11:08:57Z
dc.date.issued2010
dc.departmentTrakya Üniversitesien_US
dc.description.abstractA novel carbonate-modified bis(4-glycidyloxy phenyl) phenyl phosphine oxide (CBGPPO) was synthesized to prepare phosphine oxide based polyurethane/silica nanocomposites. Spherical silica particles were prepared according to Stober method and modified with cyclic carbonate functional silane coupling agent (CPS) to improve the compatibility of silica particles and organic phase. The cyclic carbonate-modified epoxy resins and silica particles were used to prepare hybrid coatings using hexamethylene diamine as a curing agent. The cupping, impact and gloss measurements were performed on aluminum panels, and the tensile test, gel content, thermal and morphological analyses were conducted on the free films. No damage was observed in the impact strength of the coatings. Incorporation of silica and CBGPPO into formulations increased modulus and hardness of the coating making the material more brittle. It was also observed that, the thermal stability of hybrid coatings enhanced with the addition of silica and CBGPPO. (C) 2010 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTUBITAK (The Scientific & Technological Research Council of Turkey) [106T083]en_US
dc.description.sponsorshipThis work was supported by TUBITAK (The Scientific & Technological Research Council of Turkey) Research Project under grant project number: 106T083.en_US
dc.identifier.doi10.1016/j.porgcoat.2010.07.010
dc.identifier.endpage375en_US
dc.identifier.issn0300-9440
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-78049481459en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage366en_US
dc.identifier.urihttps://doi.org/10.1016/j.porgcoat.2010.07.010
dc.identifier.urihttps://hdl.handle.net/20.500.14551/22626
dc.identifier.volume69en_US
dc.identifier.wosWOS:000284814200010en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofProgress In Organic Coatingsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectNanocompositesen_US
dc.subjectPolyurethanesen_US
dc.subjectStructure-Property Relationsen_US
dc.subjectNanoparticlesen_US
dc.subjectFunctionalized-Silicaen_US
dc.subjectChemical Fixationen_US
dc.subjectEpoxyen_US
dc.subjectPolymersen_US
dc.subjectResinsen_US
dc.subjectNanoparticlesen_US
dc.subjectCoatingsen_US
dc.subjectSizeen_US
dc.subjectCo2en_US
dc.titlePreparation and characterization of phosphine oxide based polyurethane/silica nanocomposite via non-isocyanate routeen_US
dc.typeReview Articleen_US

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