Interfacial composition and formation of w/o microemulsion with different amphiphiles and oils

Küçük Resim Yok

Tarih

2004

Yazarlar

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier Science Bv

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Microemulsions were produced by mixing different combinations of the non-ionic surfactants Triton X-100 and Triton X-405, n-alkanes (C6, C7, C8 and C10) and benzene as oils, n-alcohols (C5 and C7) as cosurfactants with water. The influence of chainlength of the alkanes and alcohols on water solubilization behavior of these systems has been investigated. The solubilization of water in a particular microemulsion is governed by the partitioning of alcohols among oil, water and interfacial phases, depending on the chainlength and nature of oil and alcohol, and their interaction with the surfactant. The molar ratio of alcohol to surfactant at the droplet interface increased with the length of the oil chain. The free energy changes accompanying cosurfactant adsorption at the interface have also been computed. (C) 2004 Elsevier B.V. All rights reserved.

Açıklama

Anahtar Kelimeler

Cosurfactant, Interface, Microemulsion, Solubilization, Surfactant, Thermodynamic Properties, Phase-Behavior, Cosurfactant, Surfactants, Systems

Kaynak

Colloids And Surfaces A-Physicochemical And Engineering Aspects

WoS Q Değeri

Q3

Scopus Q Değeri

Q1

Cilt

247

Sayı

1-3

Künye