Experimental Investigation of Cationic Gemini Surfactants: Self-Assembly, Corrosion Inhibition, Foaming and Dye Solubilization Properties

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dc.authorid/0000-0003-3875-066X
dc.contributor.authorKasapoglu, Sinem
dc.contributor.authorBatigoc, Cigdem
dc.contributor.authorBoz, Mesut
dc.contributor.authorTetik, Ovul
dc.date.accessioned2024-06-12T10:58:52Z
dc.date.available2024-06-12T10:58:52Z
dc.date.issued2023
dc.departmentTrakya Üniversitesien_US
dc.description.abstractIn this study, two cationic gemini surfactants 12-3-12 and 12-3(OH)-12 were synthesized in our labrotory. The critical micelle concentration (CMC) values of synthesized surfactants were determined by conductivity measurements. The aggregation number (Nagg) of micelles was calculated using the pyrene probe fluorescence method. It was been investigated the corrosion effect of cationic gemini surfactants were denoted as 12-3-12 and 12-3(OH)-12 for carbon steel in 1 M HCl. The inhibition effect was investigated using weight loss, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP) and scanning electron microscopy (SEM) techniques. It has been determined that both surfactants showed the best inhibitory effect at low concentrations. The foaming capacity (FC) and the foam stability (FS) of gemini surfactants were studied by measuring the foam volume for 0.5 % (w/v) surfactant solutions and it was observed that the foaming properties of 12-3(OH)-12 gemini surfactant were better. The solubility capability of both surfactants was tested with the water-insoluble dye Sudan Red B and it was observed that the solubility increased significantly over the CMC value of the cationic gemini surfactants. Finally, the corrosion effect, foam capacity and foam stability and effects on paint solubility of the synthesized surfactants were obtained at very low concentrations.en_US
dc.description.sponsorshipTrakya University [TUBAP-2019/217, TUBAP-2020/67]en_US
dc.description.sponsorshipWe gratefully acknowledge the financial support of The Scientific Research Project Fund of Trakya University [TUEBAP-2019/217] and [TUEBAP-2020/67].en_US
dc.identifier.doi10.1002/slct.202301309
dc.identifier.issn2365-6549
dc.identifier.issue27en_US
dc.identifier.scopus2-s2.0-85165431673en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/slct.202301309
dc.identifier.urihttps://hdl.handle.net/20.500.14551/20221
dc.identifier.volume8en_US
dc.identifier.wosWOS:001031865000001en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofChemistryselecten_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCritical Micelle Concentrationen_US
dc.subjectCorrosion Inhibitoren_US
dc.subjectDye Solubilizationen_US
dc.subjectFoaming Capacityen_US
dc.subjectGemini Surfactanten_US
dc.subjectMild-Steel Corrosionen_US
dc.subjectPhysicochemical Propertiesen_US
dc.subjectAqueous-Solutionen_US
dc.subjectHydroxyl-Groupsen_US
dc.subjectCarbon-Steelen_US
dc.subjectAggregationen_US
dc.subjectAdsorptionen_US
dc.subjectMixturesen_US
dc.subjectBehavioren_US
dc.subjectChlorideen_US
dc.titleExperimental Investigation of Cationic Gemini Surfactants: Self-Assembly, Corrosion Inhibition, Foaming and Dye Solubilization Propertiesen_US
dc.typeArticleen_US

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