Determination of Optical Band Gap Energies of CS/MWCNT Bio-nanocomposites by Tauc and ASF Methods

Küçük Resim Yok

Tarih

2020

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier Ltd

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

In the quest for developing new and advanced technologies, semiconductor band gap engineering is critical. In this study, chitosan/multi-walled carbon nanotube (CS/MWCNT) bio-nanocomposite films were prepared using a simple, environmental-friendly and cost-effective method, and the changes occurring in optical band gap energies (Eg) were examined with Tauc and Absorbance Spectrum Fitting (ASF) methods. The results of both models were found to be very close to each other. The optical and electrical properties of the bio-nanocomposites were significantly improved, which make them promising materials for ultraviolet protection, coating and optoelectronic applications. In addition, Urbach energies (Eu) (Band tails) and optical parameters of CS/MWCNT bio-nanocomposites such as refractive index (n), absorption (?) and extinction (k) coefficient were investigated. Urbach energy levels and refractive index values were increased with the increase of MWCNT content in CS matrix. The obtained low band gap energies of the composites by adding MWCNT were interpreted as evidence that the electrical conductivity of the composites is increased and this behavior was found to be consistent with surface conductivity measurements of the composites. © 2020 Elsevier B.V.

Açıklama

Anahtar Kelimeler

Asf Method; Chitosan Bio-Nanocomposites; Conductive Bio-Nanocomposites; Optical Band Gap; Refractive Index; Tauc Method; Urbach Energy; Uv Protection, Carbon Films; Cost Effectiveness; Electric Conductivity; Multiwalled Carbon Nanotubes (Mwcn); Nanocomposite Films; Nanocomposites; Optical Band Gaps; Refractive Index; Cost-Effective Methods; Electrical Conductivity; Environmental-Friendly; Optical And Electrical Properties; Optical Band Gap Energy; Optoelectronic Applications; Semiconductor Band Gap; Ultraviolet Protection; Energy Gap

Kaynak

Synthetic Metals

WoS Q Değeri

Scopus Q Değeri

Q1

Cilt

269

Sayı

Künye