VO(IV) complexes of N2O2 tetradentate ligands with flexible alkyl spacer: synthesis, characterization and antibacterial activities

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dc.contributor.authorUlucam, Guhergul
dc.contributor.authorYenturk, Busra
dc.date.accessioned2024-06-12T11:13:55Z
dc.date.available2024-06-12T11:13:55Z
dc.date.issued2020
dc.departmentTrakya Üniversitesien_US
dc.description.abstractThree Schiff base ligands which contain N2O2 donors and their oxo-vanadium(IV) complexes have been synthesized. The ligand C14H16N2O2 has obtained as a result of the reaction of 1,4-diaminobutane with 2-furan-carboxyaldehyde within the framework of Schiff base condensation method. The same reaction path is followed replacing 1,4-diaminobutane by 1,6-diaminohexane and 1,8-diaminooctane in separate reactions to obtain the two other new ligands. Then, the synthesized ligands are employed to attain the oxo-vanadium(IV) complexes as results of their reactions with VOSO4 center dot H2O. The ligands have been characterized by FTIR, C-13 NMR, H-1 NMR, and LC/ESI-MS. The VO(IV) complexes have been elucidated by FTIR, LC/ESI-MS, energy dispersive X-ray spectroscopy, thermogravimetric methods, and the conductivity and magnetic susceptibility measurements. The antibacterial activities of the ligands and their complexes have been determined on the microorganisms which are aligned as Escherichia coli ATCC 25922, Salmonella typhimurium ATCC 14028, Staphylococcus aureus ATCC 25923, Listeria monocytogenes ATCC 19115 and Bacillus cereus ATCC 11778. The complexes, in general, appeared to be more active than their parent ligands. All the activities can be classified as moderate in comparison with the corresponding antibiotic effect on the same bacteria.en_US
dc.description.sponsorshipResearch Fund of Trakya University [TUBAP-2016/22]en_US
dc.description.sponsorshipThe study was supported by the Research Fund of Trakya University with the project TUBAP-2016/22.en_US
dc.identifier.endpage532en_US
dc.identifier.issn0376-4710
dc.identifier.issn0975-0975
dc.identifier.issue4en_US
dc.identifier.startpage526en_US
dc.identifier.urihttps://hdl.handle.net/20.500.14551/23730
dc.identifier.volume59en_US
dc.identifier.wosWOS:000539157700002en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherNatl Inst Science Communication-Niscairen_US
dc.relation.ispartofIndian Journal Of Chemistry Section A-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSchiff Baseen_US
dc.subjectAntibacterial Activityen_US
dc.subjectOxo-Vanadium(IV) Complexesen_US
dc.subjectFuranen_US
dc.subjectSchiff-Base Polymersen_US
dc.subjectSpectral Characterizationen_US
dc.subjectMetal-Complexesen_US
dc.subjectVanadiumen_US
dc.subjectDesignen_US
dc.subjectDyesen_US
dc.titleVO(IV) complexes of N2O2 tetradentate ligands with flexible alkyl spacer: synthesis, characterization and antibacterial activitiesen_US
dc.typeArticleen_US

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