CONDENSATION OF ETHYL ACETOACETATE WITH NAPHTHALENE-DIOLS - THE SYNTHESIS OF SOME NOVEL COUMARINS AND CHROMONES .1.
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Tarih
1994
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Yayıncı
Soc Chimique Belgique
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In Simonis reaction with ethyl acetoacetate naphthalene-2,6-diol gives 8-hydroxy-3-methyl-1 H-naphtho[2,1-b]pyran-l-one and naphthalene-2,7-diol gives the related 9-hydroxy isomer. In Pechman reactions, the former diet yields a coumarin, 8-hydroxy-1-methyl-3H-naphtho[2,1-b]-pyran-3-one, with the corresponding orientation, but the latter diol gives a coumarin, 8-hydroxy-4-methyl-2H-naphtho[2,3-b]-pyran-2-one, with an unusual linear annelation pattern.
Açıklama
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[No Keywords]
Kaynak
Bulletin Des Societes Chimiques Belges
WoS Q Değeri
N/A
Scopus Q Değeri
Cilt
103
Sayı
12