Silver Ion-Assisted Ring Expansions in Different Solvent Systems
Küçük Resim Yok
Tarih
2009
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Tubitak Scientific & Technological Research Council Turkey
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Several ring expansion products carrying vinylic bromo functionality were synthesized by opening of the geminal dibromobicyclo[n.1.0]alkanes ring. Dibromocarbene was formed from bromoform and potassium tert-butoxide in hexane. Its reaction with various cyclic alkenes was the resultant dibromobicyclo[n.1.0]alkanes. Then, opening was performed using AgNO3 in various solvent systems, such as acetic acid/DMSO, acetic acid/DMF, CH3OH/acetone, and H2O/DMF.
Açıklama
Anahtar Kelimeler
Carbene, Bicyclic Compound, Ring Opening, Ring Expansion, Vinylic Halide, Catalyzed-Reactions, Chirality
Kaynak
Turkish Journal Of Chemistry
WoS Q Değeri
Q3
Scopus Q Değeri
Cilt
33
Sayı
1
