Rapid [3,3] sigmatropic rearrangements of allylic thiono chloroformates
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Date
1999
Authors
Journal Title
Journal ISSN
Volume Title
Publisher
Pergamon-Elsevier Science Ltd
Access Rights
info:eu-repo/semantics/closedAccess
Abstract
Treatment of allylic alcohols with thiophosgene and pyridine gives thiolo chloroformates directly at room temperature, presumably via very rapid [3,3] sigmatropic rearrangements of thiono chloroformates. Synthesis of allyl thiono chloroformate from allyl alcohol, sodium hydride and thiophosgene at low temperature and warming up to room temperature supports this finding. (C) 1999 Elsevier Science Ltd. All rights reserved.
Description
Keywords
Rearrangements, Alcohols, Thiocarbonyl, Thiocarbamate, Dithiocarbonates, Alcohols, Acids
Journal or Series
Tetrahedron Letters
WoS Q Value
Q2
Scopus Q Value
Q3
Volume
40
Issue
46
