Synthesis, spectroscopic and spectrophotometric study of BODIPY appended crown ether sensor for ion detection

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dc.authoridYılmaz, Halil/0000-0001-5190-6628
dc.authorwosidHayvalı, Zeliha/AAF-3340-2020
dc.authorwosidYılmaz, Halil/AAR-5722-2020
dc.contributor.authorSahin, Duygu
dc.contributor.authorYilmaz, Halil
dc.contributor.authorHayvali, Zeliha
dc.date.accessioned2024-06-12T10:54:54Z
dc.date.available2024-06-12T10:54:54Z
dc.date.issued2016
dc.departmentTrakya Üniversitesien_US
dc.description.abstractA novel fluoroionophore compound was synthesized from a boron dipyrromethene (BODIPY) fluorophore and 40-formylbenzo-15-crown-5 ionophore groups. Photophysical properties of the BODIPY-crown compound were studied with UV-Vis and fluorescence spectroscopy. The effect of metalic cations (Li+, Na+, K+, Mg2+, Ca2+, Ba2+, Al3+, Fe3+, Cu2+, Co2+, Zn2+, Ag+, Hg2+, Pb2+) on the absorption and fluorescence spectra of compound 2 was investigated. Blue shifts were detected in UV-Vis spectra upon addition of some metal ions (Al3+ > Fe3+ > Na+). At the same time, the emission intensity of this complex increased due to binding of Na+ ion to the benzo crown cavity. Additionally, a decrease in the intensity of the 630 nm emission peak and an increase in the intensity of the 570 nm emission peak was observed in the fluorescence emission spectra following addition of Al3+ and Fe3+ ions.en_US
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK) [TBAG 113Z523]en_US
dc.description.sponsorshipThe authors gratefully acknowledge the financial assistance of the Scientific and Technical Research Council of Turkey (TUBITAK), Grant No: TBAG 113Z523.en_US
dc.identifier.doi10.1007/s11164-016-2466-2
dc.identifier.endpage6350en_US
dc.identifier.issn0922-6168
dc.identifier.issn1568-5675
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-84957605330en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage6337en_US
dc.identifier.urihttps://doi.org/10.1007/s11164-016-2466-2
dc.identifier.urihttps://hdl.handle.net/20.500.14551/19212
dc.identifier.volume42en_US
dc.identifier.wosWOS:000385201000012en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofResearch On Chemical Intermediatesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBODIPYen_US
dc.subjectCrown Ethersen_US
dc.subjectChemosensoren_US
dc.subjectFluorescenceen_US
dc.subjectMetal Ionsen_US
dc.subjectBoron Dipyrromethene Dyesen_US
dc.subjectFluorescent Chemosensoren_US
dc.subjectCation Complexationen_US
dc.subjectCharge-Transferen_US
dc.subjectDerivativesen_US
dc.subjectAzacrownen_US
dc.subjectBehavioren_US
dc.subjectBindingen_US
dc.subjectBenzo-15-Crown-5en_US
dc.subjectExtractionen_US
dc.titleSynthesis, spectroscopic and spectrophotometric study of BODIPY appended crown ether sensor for ion detectionen_US
dc.typeArticleen_US

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