Thermodynamics of dissociation and micellization of sodium, calcium, aluminum, and tin stearates in mixed organic solvents

Küçük Resim Yok

Tarih

1997

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Springer

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Sodium, calcium, aluminum, and tin stearates behave as weak electrolytes in dilute solutions (60% benzene + 40% methanol, vol/vol) below the critical micelle concentration, and conductance data can be explained on the basis of Ostwald's formula and the Debye-Huckel theory of weak electrolytes. Dissociation constants and thermodynamic parameters for dissociation and micellization of these soaps were also evaluated. Micellization was spontaneous and predominant over the dissociation process.

Açıklama

Anahtar Kelimeler

Aluminum And Tin Stearate, Calcium, Conductance, Critical Micelle Concentration, Dissociation, Micellization, Sodium, Thermodynamics, Praseodymium

Kaynak

Journal Of The American Oil Chemists Society

WoS Q Değeri

Q1

Scopus Q Değeri

Q2

Cilt

74

Sayı

7

Künye