A Convenient Synthesis of 2-Azido and 2-Thiocyanato-2,3-Unsaturated Cyclic Ketones

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dc.authoridZaim, Omer/0000-0002-3472-5611;
dc.authorwosidZaim, Omer/Q-7770-2019
dc.authorwosidZaim, Ömer/AAI-1470-2021
dc.contributor.authorBoz, Mesut
dc.contributor.authorZaim, Oemer
dc.contributor.authorEsen, Hilal
dc.date.accessioned2024-06-12T10:54:07Z
dc.date.available2024-06-12T10:54:07Z
dc.date.issued2009
dc.departmentTrakya Üniversitesien_US
dc.description.abstract2-Azido and 2-thiocyanato-2,3-unsaturated ketones were synthesized by utilizing functionalization of 5- or 6-membered cycloalkane-1,2-diones, namely diosphenols, with dimethylthiocarbomoyl chloride, which activates the system towards reaction with nucleophiles in acidic conditions. Replacement of the enolic oxygen of the diosphenols with azide and thiocyanate may be achieved by treating their dimethylthiocarbamates with sodium azide or potassium thiocyanate in boiling acetonitrile/acetic acid.en_US
dc.description.sponsorshipTrakya University Research Funden_US
dc.description.sponsorshipWe are grateful to The Trakya University Research Fund for its financial support of this research.en_US
dc.identifier.doi10.3906/kim-0811-12
dc.identifier.endpage65en_US
dc.identifier.issn1300-0527
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-61849179609en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage59en_US
dc.identifier.trdizinid89148en_US
dc.identifier.urihttps://doi.org/10.3906/kim-0811-12
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/89148
dc.identifier.urihttps://hdl.handle.net/20.500.14551/18933
dc.identifier.volume33en_US
dc.identifier.wosWOS:000262865000006en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakTR-Dizinen_US
dc.language.isoenen_US
dc.publisherTubitak Scientific & Technological Research Council Turkeyen_US
dc.relation.ispartofTurkish Journal Of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectAzidesen_US
dc.subjectThiocyanatesen_US
dc.subjectEnolsen_US
dc.subjectDeoxygenationen_US
dc.subject1,2-Cyclic Diketonesen_US
dc.subjectDiosphenolsen_US
dc.subjectElaborationen_US
dc.subjectReplacementen_US
dc.titleA Convenient Synthesis of 2-Azido and 2-Thiocyanato-2,3-Unsaturated Cyclic Ketonesen_US
dc.typeArticleen_US

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