A new approach to the ring opening reactions of 2,7,7-trimethyl-3,3-dibromotricyclo[4.1.1.$0^{2,4}$] octane

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dc.contributor.authorBalcı, Metin
dc.contributor.authorŞenol, Zekir
dc.contributor.authorZaim, Ömer
dc.date.accessioned2024-06-12T10:18:21Z
dc.date.available2024-06-12T10:18:21Z
dc.date.issued2005
dc.departmentTrakya Üniversitesien_US
dc.description.abstractThe reaction of $alpha$−pinene and dibromocarbene produced a fairly unstable product, 2,7,7-trimethyl-3,3-dibromotricyclo[4.1.1.$0^{2,4}$]octane, from which 3-bromo-7,7-dimethyl-2-methylenebicyclo[4,1,1]oct-3-ene and 3-bromo-2,7,7-trimethylbicyclo [4,1,1]octa-2,4-diene were obtained in chloroform at room temperature and in various other media and conditions. Two new compounds, 3-bromo-2,7,7-trimethylbicyclo [4.1.1]oct-3-en-2-ol and 2-(4-bromo-5-methylcyclohepta-3,5-dien-1-yl) propan-2-ol, were observed in aqueous acetone in addition to the previous two. The stability and formation mechanism of the formed products are discussed.en_US
dc.identifier.endpage538en_US
dc.identifier.issn1300-0527
dc.identifier.issn1303-6130
dc.identifier.issue5en_US
dc.identifier.startpage531en_US
dc.identifier.trdizinid49056en_US]
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/49056
dc.identifier.urihttps://hdl.handle.net/20.500.14551/15482
dc.identifier.volume29en_US
dc.indekslendigikaynakTR-Dizinen_US
dc.language.isoenen_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleA new approach to the ring opening reactions of 2,7,7-trimethyl-3,3-dibromotricyclo[4.1.1.$0^{2,4}$] octaneen_US
dc.typeArticleen_US

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