Micellization, aggregation, interaction, and solubilization behaviors of mixed solutions of cationic gemini and nonionic surfactants

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dc.contributor.authorSarikaya Yildiz, Ikbal
dc.contributor.authorBilgen, Selcuk
dc.contributor.authorAkbas, Halide
dc.date.accessioned2024-06-12T10:51:02Z
dc.date.available2024-06-12T10:51:02Z
dc.date.issued2024
dc.departmentTrakya Üniversitesien_US
dc.description.abstractThe micellization properties of mixed aqueous solutions of a cationic gemini surfactant (CGS) and Triton X-100, a conventional non-ionic surfactant, with various mole fractions, were determined by measuring the surface tension at different temperatures. Various theoretical models were used to analyze the behavior of this mixed system. The interactions between CGS and Triton X-100 were determined to be non-ideal and synergistic. The calculated interaction parameters (beta M) have negative values at all temperatures and for all mole fractions, showing attractive interactions. It was found that increasing the mole fraction of Triton X-100 significantly increased the synergistic effect (more negative values). Micellar aggregation number (Nagg) values of pure surfactants and their mixtures in different ratios were obtained with the steady-state fluorescence quenching method. Furthermore, the molar solubilization ratio of Sudan III organic dye in all surfactants aqueous systems was obtained using UV-Visible spectrophotometry. At concentrations above critical micelle concentration, the solubility of Sudan III in water was substantially increased linearly for all systems and it was observed that the enhancement was even more significant for mixed surfactant systems.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkiye (TUBITAK) [117Z605]en_US
dc.description.sponsorshipThe Scientific and Technological Research Council of Turkiye (TUBITAK), Grant/Award Numberen_US
dc.identifier.doi10.1002/jsde.12755
dc.identifier.issn1097-3958
dc.identifier.issn1558-9293
dc.identifier.scopus2-s2.0-85190459135en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.urihttps://doi.org/10.1002/jsde.12755
dc.identifier.urihttps://hdl.handle.net/20.500.14551/18197
dc.identifier.wosWOS:001198665800001en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofJournal Of Surfactants And Detergentsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAggregation Numberen_US
dc.subjectCationic Gemini Surfactanten_US
dc.subjectCritical Micelle Concentrationen_US
dc.subjectNonionic Surfactanten_US
dc.subjectSolubilizationen_US
dc.subjectPolycyclic Aromatic-Hydrocarbonsen_US
dc.subjectIonic Liquiden_US
dc.subjectSystemsen_US
dc.subjectSingleen_US
dc.subjectWateren_US
dc.titleMicellization, aggregation, interaction, and solubilization behaviors of mixed solutions of cationic gemini and nonionic surfactantsen_US
dc.typeArticleen_US

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