A new approach to the ring opening reactions of 2,7,7-trimethyl-3,3-dibromotricyclo[4.1.1.02,4]octane

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dc.authoridZaim, Omer/0000-0002-3472-5611;
dc.authorwosidŞenol, Zeynep Mine/HHC-9326-2022
dc.authorwosidZaim, Omer/Q-7770-2019
dc.authorwosidZaim, Ömer/AAI-1470-2021
dc.contributor.authorSenol, Z
dc.contributor.authorZaim, Ö
dc.contributor.authorBalci, M
dc.date.accessioned2024-06-12T11:17:32Z
dc.date.available2024-06-12T11:17:32Z
dc.date.issued2005
dc.departmentTrakya Üniversitesien_US
dc.description.abstractThe reaction of a-pinene and dibromocarbene produced a fairly unstable product, 2,7,7-trimethyl-3,3-dibromotricyclo[4.1.1.0(2,4)] octane, from which 3-bromo-7,7-dimethyl-2-methylenebicyclo[4,1,1]oct-3-ene and 3-bromo-2,7,7-trimethylbicyclo [4,1,1]octa-2,4-diene were obtained in chloroform at room temperature and in various other media and conditions. Two new compounds, 3-bromo-2,7,7-trimethylbicyclo [4.1.1]oct-3-en-2-ol and 2-(4-bromo-5-methyleyclohepta-3,5-dien-1-yl) propan-2-ol, were observed in aqueous acetone in addition to the previous two. The stability and formation mechanism of the formed products are discussed.en_US
dc.identifier.endpage538en_US
dc.identifier.issn1300-0527
dc.identifier.issue5en_US
dc.identifier.startpage531en_US
dc.identifier.urihttps://hdl.handle.net/20.500.14551/24751
dc.identifier.volume29en_US
dc.identifier.wosWOS:000233674200010en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherTubitak Scientific & Technological Research Council Turkeyen_US
dc.relation.ispartofTurkish Journal Of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAluminum-Hydrideen_US
dc.subjectAlpha-Pineneen_US
dc.subjectDibromocarbeneen_US
dc.subjectGenerationen_US
dc.subjectReductionen_US
dc.subjectLithiumen_US
dc.titleA new approach to the ring opening reactions of 2,7,7-trimethyl-3,3-dibromotricyclo[4.1.1.02,4]octaneen_US
dc.typeArticleen_US

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