Studies on Synthesis, Characterization, Micellar Features, and Solubilization of Four Novel Cationic Gemini Surfactants

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dc.contributor.authorSarikaya, Ikbal
dc.contributor.authorBilgen, Selcuk
dc.contributor.authorUnver, Yasemin
dc.contributor.authorAkbas, Halide
dc.date.accessioned2024-06-12T11:20:40Z
dc.date.available2024-06-12T11:20:40Z
dc.date.issued2021
dc.departmentTrakya Üniversitesien_US
dc.description.abstractFour novel cationic gemini surfactants with the same hydrocarbon chain lengths but different spacers have been investigated in this article. After these cationic gemini surfactants have been synthesized, their structures have been characterized by appropriate spectroscopic methods. By determining their Krafft temperatures, the effects of spacer type and structure on Krafft temperature have been examined. Micellization behaviors of the cationic gemini surfactants have been researched at temperatures above the determined Krafft temperatures. Critical micelle concentration (cmc), counterion binding degree (beta), and counterion dissociation degree (alpha) and standard enthalpy change (Delta H degrees(mic)), standard Gibbs free energy change (Delta G degrees(mic)), and standard entropy change (Delta S degrees(mic)) of micellization of cationic gemini surfactants have been calculated. The solubilization capabilities of these surfactants have been evaluated according to the molar solubilization ratio (MSR). Additionally, the emulsification powers have been measured.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [117Z605]en_US
dc.description.sponsorshipThis study was supported by The Scientific and Technological Research Council of Turkey (TUBITAK, project no: 117Z605).en_US
dc.identifier.doi10.1021/acs.jced.1c00030
dc.identifier.endpage1532en_US
dc.identifier.issn0021-9568
dc.identifier.issn1520-5134
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-85103333959en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1522en_US
dc.identifier.urihttps://doi.org/10.1021/acs.jced.1c00030
dc.identifier.urihttps://hdl.handle.net/20.500.14551/25723
dc.identifier.volume66en_US
dc.identifier.wosWOS:000629163700030en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofJournal Of Chemical And Engineering Dataen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keywords]en_US
dc.titleStudies on Synthesis, Characterization, Micellar Features, and Solubilization of Four Novel Cationic Gemini Surfactantsen_US
dc.typeArticleen_US

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